李良修教授 研究室:C4001     實驗室:C4001 電話:(07)5252000 ext e-mail:lelish@mail.nsysu.edu.tw
教授(1994) 副教授(1984) 美國克雷姆森大學博士(1984) 清華大學理學士(1977)

研究興趣

本研究室之主要工作為研究金屬配位化合物在激態下的反應及其反應動力學。

研究方法包括：配位基的選擇及合成，金屬配位化合物的合成及鑑定（光譜、磁性等的測量），光化學反應形態的探討，光產率的測定，並利用配位場論模型計算以解釋實驗結果。

研究目標：從理論計算與實驗結果的印証了解金屬配位化合物中金屬和配位基之間的作用，歸納出在激態下，配位基對其化性的影響，進而設計具實用價值之光催化反應系統。目前我們在籠型三價鈷化合物之光催化反應上已有具體成果。

代表著作

1. Huang, M. F.; Lee, L. "The Temperate Dependence Study of Oscillation Period of BR Reaction" Chemistry (The Chinese Chem. Soc., Taiwan, China) 1993, 51, 71.

2. Lee, L.; Yuan, C. H. "Photosensitization Study of Cage-like Metal Complexes with Hexadentate Ligands, tptn and tpen. Part 1. Photochemistry and Spectroelectrochemistry of Iron(ll), Cobalt(lll) and Nickel(ll) Complexes" J. Photochem.Photobio. A: Chem. 1993, 70, 253.

3. Lee, L.; Yuan, C. H. "Photosensitization Study of Cage-like Metal Complexe with Hexadentate Ligands, tptn and tpen. Part 2. Electron Transfer Photosensitization via lon Pairs: Cobalt(lll)(tptn)-iodide lon and Cobalt(lll)(tpen)-iodide lon Systems" J. Photochem. Photobio. A: Chem. 1993, 70, 261.

4. Hwang, W. S.; Lee. L.; Yu. W. R. "Electrooxdation of Tricarbonyl( N ,N-diphenylcyclohexadienecarboxamide)iron Complexes. Reversibility of Electron Transfer and Free Energy Change" J. Chin. Chem. Soc. 1993, 40, 263.

5. Lee, L. ''Angular Overlap Model Approach to Explain the Trans-Effect in d8 Square Planar Metal Complexes" J. Chem. Edu. 1994, 71, 644.

6. Lee. L.; Wang, C. H. "Photoaquation and Aquation of Trans- Dichlorobis(bipyridine)rethenium(III)" J. Photochem.Photobio. A: Chem. 1994, 79, 163.

7. Lin, J. T.; Sun, S. -S.; Wu, J. J.; Lee, L.; Lin, K. -J.; Huang, Y. F. "Dinuclear Metal Carbonyls Bridged by Pyridyl Ligands Incorporating an Alkyne Entity" Inorg. Chem. 1995, 34, 2323.

8. 1. D. L. Wang, W. S. Hwang, L. C. Liang, Lein. I. Wang, L. Lee, M. Y. Chiang, "Reaction of Thienyl Schiff Base with Diiron Nonacarbonyl" Organometallics 1997, 16, 3109.

9. D. L. Wang, W. S. Hwang, L. Lee, M. Y. Chiang; "Reaction of N-(3-methyl-2-thienylmethylidene) aniline with Diiron Nonacarbonyl: Cyclometalation induced methyl migration, imidoyl complex formation, and hydrogenation" J. Organometallic Chem. 1997, 579, 211.

10. W. S. Hwang, C. J. Hwang, D. L. Wang, L. Lee, M. Y. Chiang; "Synthesis and Structure of 1-(2-Thienylmethyl)-2-(2-thienyl)bezimidazole and its Cu(I) and Ag(I) Complexes" J. Chin. Chem. Soc. 1998, 45, 555.

11. T. Y. Dong, L. Lee, C. H. Cheng, L. S. Chang, M. Y. Chiang; "Complexation behavior of 1,1”:1’,1”’-bis(1,4 ,10 13-tetraoxa-7,16-diazacyclooctadecane-7,16-diyldimethyl)bisferrocene" J. Organomettallic Chem. 2001, 625, 173.

12. L. Lee; "Introduction to Inorganic Photochemistry", Chemistry (The Chinese Chem. Soc. Taipei), 2002, 60(4), 653.

13. C. H. Cheng, F. D. Yen, L. Lee; "Photochemical Reactions of Methanol or Isopropanol and Cage-like Co(III) Complexes" Chemistry (The Chinese Chem. Soc. Taipei), 2003.

14. T. Y. Dong, M. C. Lin, L. Lee, C. H. Cheng, S. H. Peng, G. H. Lee; "Pronounced Effects of Grinding on Rates of Intramolecular Electron Transfer in Mixed-Valence 1^’,2^’,1^’’’,2^’’’-Tetranaphthylmethyl- and 1^’,3^’,1^’’’,3^’’’- Tetranaphthylmethyl-Biferrocenium Triiodides" J. Organomettallic Chem. 2003, 679, 181-193.

15. T. Y. Dong, Kellen Chen, M. C. Lin, and L. Lee; Toward the Development of Molecular Wires: Ruthenium(II) Terpyridine Complexes Containing Polyferrocenyl as a Spacer; Organometallics ,24, 4198-4206(2005).----(SCI)

16. S. F. Ko, C. C. Huang, M. J. Hsieh, S. H. Ng, C. C. Lee, C. C. Lee, T. K. Lin, M. C. Chen, M. C. Chen, L. Lee, ³¹P MR Spectroscopic Assessment of Muscle in Patients with Myasthenia Gravis befor and after Thymectomy: Initial Experience, Radiology 2008, 247(1), 162.

17. L. Lee, “A Simplified Approach to the Basis Functions of Symmetry Operations and Terms of Metal Complexes in an Octahedral Field with d1 to d9 Configurations”, J. Chem. educ. 87(2), 2010, 172.

其他著作

1. 李良修，走過帕金森幽谷，天下文化，台北，1999。

2. 李良修，我懂了！量子力學，商周出版社，台北，2004。

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